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Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов

А. В. Салин 1 *
А. В. Салин
* salin555@mail.ru
, 
А. А. Шабанов 1
А. А. Шабанов
Published 2025-12-10
Review , Volume 75, Issue 2, 401-441
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Салин А. В., Шабанов А. А. Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов // Russian Chemical Bulletin. 2025. Vol. 75. No. 2. pp. 401-441.
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Салин А. В., Шабанов А. А. Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов // Russian Chemical Bulletin. 2025. Vol. 75. No. 2. pp. 401-441.
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TY - JOUR
UR - https://russchembull.colab.ws/publications/65
TI - Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов
T2 - Russian Chemical Bulletin
AU - Салин, А. В.
AU - Шабанов, А. А.
PY - 2025
DA - 2025/12/10
PB - Известия Академии наук. Серия химическая
SP - 401-441
IS - 2
VL - 75
ER -
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@article{2025_Салин,
author = {А. В. Салин and А. А. Шабанов},
title = {Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов},
journal = {Russian Chemical Bulletin},
year = {2025},
volume = {75},
publisher = {Известия Академии наук. Серия химическая},
month = {Dec},
url = {https://russchembull.colab.ws/publications/65},
number = {2},
pages = {401--441}
}
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Салин, А. В., and А. А. Шабанов. “Третичные фосфины в органокатализе реакций электронодефицитных алкенов, алкинов и алленов.” Russian Chemical Bulletin, vol. 75, no. 2, Dec. 2025, pp. 401-441. https://russchembull.colab.ws/publications/65.

Keywords

Алкены
Алкины
аллены
асимметрический синтез
органокатализ
природные соединения
третичные фосфины

Abstract

Органокатализ фосфинами успешно решает многие задачи, стоящие перед современным органическим синтезом и медицинской химией, позволяя с высокой атомной экономией, хемо- и стереоселективно получать целевые соединения с новыми связями углерод—углерод и углерод—гетероатом. В настоящем обзоре обсуждаются основные методологические аспекты, а также современные тенденции использования третичных фосфинов в органокатализе реакций алкенов, алкинов и алленов, активированных электроноакцепторными группами. Рассмотрены примеры использования данных реакций в качестве ключевых стадий в многостадийных синтезах сложных биологически активных природных соединений.

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